\documentclass{article}
\usepackage{xepersian}
\begin{document}
\listoffigures
\begin{figure}[b!]
\centering
\includegraphics[scale=.5]{Images/1.jpg}
\caption{شکل اول}
\end{figure}
\begin{figure}[b!]
\centering
\includegraphics[scale=.5]{Images/2.jpg}
\caption{شکل دوم}
\end{figure}
\begin{figure}[b!]
\centering
\includegraphics[scale=.5]{Images/3.jpg}
\caption{شکل سوم}
\end{figure}
\begin{figure}[b!]
\centering
\includegraphics[scale=.5]{Images/4.jpg}
\caption{شکل چهارم}
\end{figure}
\end{document}